If you turn the engine off when it's in gear (manual or any automatic mode), then it won't start until it has put itself in neutral next time you switch the bike on. This is worth knowing, because if your battery runs down, it may not have the power to put itself in neutral.
Once it has itself in neutral, it always defaults to D-mode on startup.
(at least that's the way the DCT on the NC bikes is programmed - I guess there is probably some hidden key combination that can change the default start-up mode, but none has come to light on the NC forums.
Mike